The stabilized substance is assigned by name to UN No. 1695.
For the unstabilized substance, see 2.2.2.2.1 of the ADN:

"Chemically unstable gases of Class 2 shall not be accepted for carriage unless the necessary precautions have been taken to prevent the possibility of a dangerous decomposition or polymerization under normal conditions of carriage or unless carried in accordance with special packing provision (r) of packing instruction P200 (10) of 4.1.4.1 of ADR, as applicable. For the precautions necessary to prevent polymerization, see special provision 386 of Chapter 3.3. To this end particular care shall be taken to ensure that receptacles and tanks do not contain any substances liable to promote these reactions."